Reaction of Propargylic Substrates wiht Organocopper Species. Synthetic Aspects

DOI: 10.1021/jo01311a037

Source and publish data:

Journal of Organic Chemistry p. 4740 - 4747 (1980)

Update date:2022-07-30

Topics:

Authors:

Macdonald, Timothy L.

Reagan, David R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01311a037

The reaction of propargylic substrates with organocopper species can yield two major products, a substituted allene or a new acetylene.This paper is a study of the factors which influence the distribution of these products in this displacement (e.g., 1-->

Full text of DOI:10.1021/jo01311a037

Products guided by the article

Product name:1-Cyclohexyl-3-methyl-hept-1-yn-3-ol

Cas No:74835-61-3

R&D Labs maybe for 74835-61-3

HEZE KINGVOLT CHEMICAL CO., LTD

Contact:86-573-82118911

Address:Juancheng Industry Park
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Junkai (Tianjin) Chemical Co., Ltd.

website:http://www.junkaichem.com

Contact:86-22-85689515

Address:Room 8-501, Building K2, The Hi-Tech Green Industrial Base, No.6, 6th Road, Hi-Tech Development Road, Tianjin Hi-Tech IndustrialPark, Tianjin, China.
Anhui Qingyun Pharmaceutical and Chemical Co.,Ltd

Contact:+86-551-63633067

Address:Shuangfeng Road Hefei Anhui

Relevant to this article

Doi:10.1039/jr9320001125
(1932)
Synthesis of chiral organotin reagents: Synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(

Doi:10.1039/b200317c
(2002)
2-(1-Adamantyl)-4-(thio)chromenone-6-carboxylic acids: Potent reversible inhibitors of human steroid sulfatase

Doi:10.1021/jm0407916
(2004)
Facile syntheses and antimicrobial studies of 6-(aryloxy/arylthio/chloroethoxy)-2,10-dichloro- 4,8-dinitro-12-trichloromethyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin 6-oxides

Doi:10.1002/jhet.5570400224
(2003)
A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

Doi:10.1039/C8SC02769B
(2018)
Synthesis of N-functionalized/NH-multisubstituted indoles, thienopyrroles, pyrroloindoles, and pyrazolopyrroles via sequential one-pot base-mediated and copper-catalyzed inter- and intramolecular amination of 2-[2-bromo(het)aryl]-3-(het)aryl-3-(methylthio)acrylonitriles

Doi:10.1021/jo501114a
(2014)

Article Doi