Reaction of Propargylic Substrates wiht Organocopper Species. Synthetic Aspects

DOI: 10.1021/jo01311a037

Source and publish data:

Journal of Organic Chemistry p. 4740 - 4747 (1980)

Update date:2022-07-30

Topics:

Authors:

Macdonald, Timothy L.

Reagan, David R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01311a037

The reaction of propargylic substrates with organocopper species can yield two major products, a substituted allene or a new acetylene.This paper is a study of the factors which influence the distribution of these products in this displacement (e.g., 1-->

Full text of DOI:10.1021/jo01311a037

Products guided by the article

Product name:1-Cyclohexyl-3-methyl-hept-1-yn-3-ol

Cas No:74835-61-3

R&D Labs maybe for 74835-61-3

Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Jiangsu Kolod Food Ingredients Co.,Ltd

Contact:86-518-85110578

Address:South of Weier Road,Guanyun Development Zone
Jurong Huaheng Natural Biological Products Factory

website:http://www.risebiochem.com

Contact:+86-13921007726

Address:Chuncheng town,Jurong city,Jiangsu province,China

Relevant to this article

Doi:10.1039/jr9320001125
(1932)
Synthesis of chiral organotin reagents: Synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(

Doi:10.1039/b200317c
(2002)
2-(1-Adamantyl)-4-(thio)chromenone-6-carboxylic acids: Potent reversible inhibitors of human steroid sulfatase

Doi:10.1021/jm0407916
(2004)
Facile syntheses and antimicrobial studies of 6-(aryloxy/arylthio/chloroethoxy)-2,10-dichloro- 4,8-dinitro-12-trichloromethyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin 6-oxides

Doi:10.1002/jhet.5570400224
(2003)
A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

Doi:10.1039/C8SC02769B
(2018)
Synthesis of N-functionalized/NH-multisubstituted indoles, thienopyrroles, pyrroloindoles, and pyrazolopyrroles via sequential one-pot base-mediated and copper-catalyzed inter- and intramolecular amination of 2-[2-bromo(het)aryl]-3-(het)aryl-3-(methylthio)acrylonitriles

Doi:10.1021/jo501114a
(2014)

Article Doi