Reaction of Propargylic Substrates wiht Organocopper Species. Synthetic Aspects

DOI: 10.1021/jo01311a037

Source and publish data:

Journal of Organic Chemistry p. 4740 - 4747 (1980)

Update date:2022-07-30

Topics:

Authors:

Macdonald, Timothy L.

Reagan, David R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01311a037

The reaction of propargylic substrates with organocopper species can yield two major products, a substituted allene or a new acetylene.This paper is a study of the factors which influence the distribution of these products in this displacement (e.g., 1-->

Full text of DOI:10.1021/jo01311a037

Products guided by the article

Product name:1-Cyclohexyl-3-methyl-hept-1-yn-3-ol

Cas No:74835-61-3

R&D Labs maybe for 74835-61-3

JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China

Relevant to this article

Doi:10.1039/jr9320001125
(1932)
Synthesis of chiral organotin reagents: Synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(

Doi:10.1039/b200317c
(2002)
2-(1-Adamantyl)-4-(thio)chromenone-6-carboxylic acids: Potent reversible inhibitors of human steroid sulfatase

Doi:10.1021/jm0407916
(2004)
Facile syntheses and antimicrobial studies of 6-(aryloxy/arylthio/chloroethoxy)-2,10-dichloro- 4,8-dinitro-12-trichloromethyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin 6-oxides

Doi:10.1002/jhet.5570400224
(2003)
A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

Doi:10.1039/C8SC02769B
(2018)
Synthesis of N-functionalized/NH-multisubstituted indoles, thienopyrroles, pyrroloindoles, and pyrazolopyrroles via sequential one-pot base-mediated and copper-catalyzed inter- and intramolecular amination of 2-[2-bromo(het)aryl]-3-(het)aryl-3-(methylthio)acrylonitriles

Doi:10.1021/jo501114a
(2014)

Article Doi