Chemical and Pharmaceutical Bulletin p. 408 - 410 (1993)
Update date:2022-08-04
Topics:
Itaya
Iida
Eguchi
Oxalyl chloride reacts with a wide range of 1,2-glycols in the presence of triethylamine to produce 1,3-dioxolan-2-ones together with 1,4-dioxane-2,3-diones; the ratio of the products largely depends on the structure of the 1,2-glycol. The formation of the cyclic carbonates may be rationalized in terms of stereoelectronically controlled cleavage of the tetrahedral intermediates.
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Doi:10.1021/jo01271a032
(1968)Doi:10.1002/jhet.5570170211
(1980)Doi:10.1016/S0040-4039(00)60577-4
(1993)Doi:10.1021/jm00185a007
(1980)Doi:10.1055/s-2004-829114
(2004)Doi:10.1039/jr9620003686
(1962)
