Journal of Organometallic Chemistry p. 393 - 402 (1980)
Update date:2022-08-03
Topics:
Walther, Dirk
Nickel(0) complex moieties with a high electron density at the central atom are able to yield stable complexes with many aromatic aldehydes. 1H NMR spectroscopic data give evidence about olefin-like bonding of the aldehyde group and indicate a high charge transfer.Chelate ligands like tetramethylethylenediamine yield stable complexes of the composition (TME)NiL (L = aldehyde, benzil, α,β-unsaturated carbonyl compounds).Some reactions and properties of typical mixed ligand complexes are described.
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