Helvetica Chimica Acta p. 1753 - 1786 (1989)
Update date:2022-08-02
Topics:
Quinkert, Gerhard
Fernholz, Erhard
Eckes, Peter
Neumann, Doris
Duerner, Gerd
The 18-membered lichen macrolide (+)-aspicilin (1) is easily built up from compounds 14, 16, 3, and 24 following the C3 + C7 + C6 +C2 = C18 pattern (see Schemes).The synthesis requires 15 steps and gives 1 in 13percent overall yield from D-mannose (2).The
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(1991)
