Helvetica Chimica Acta p. 1753 - 1786 (1989)
Update date:2022-08-02
Topics:
Quinkert, Gerhard
Fernholz, Erhard
Eckes, Peter
Neumann, Doris
Duerner, Gerd
The 18-membered lichen macrolide (+)-aspicilin (1) is easily built up from compounds 14, 16, 3, and 24 following the C3 + C7 + C6 +C2 = C18 pattern (see Schemes).The synthesis requires 15 steps and gives 1 in 13percent overall yield from D-mannose (2).The
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Doi:10.1021/ja01313a027
(1935)Doi:10.1016/0022-328X(88)80398-X
(1988)Doi:10.1007/BF00905257
(1966)Doi:10.1039/c39800000318
(1980)Doi:10.1021/ja048164t
(2004)Doi:10.1016/0008-6215(91)84158-B
(1991)
