Studies on Organic Fluorine Compounds. 36. Synthesis and Reactions of Trifluoromethylated Diphosphabenzvalene.

DOI: 10.1021/jo01311a027

Source and publish data:

Journal of Organic Chemistry p. 4683 - 4685 (1980)

Update date:2022-08-03

Topics:

Authors:

Kobayashi, Yoshiro

Fujino, Shomi

Hamana, Hiroshi

Hanzawa, Yuji

Morita, Seiji

Kumadaki, Itsumaro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01311a027

Photolysis of 2,3,5,6-tetrakis(trifluoromethyl)-1,4-diphosphabenzene (3) or its precursor (2) gave 1,3,4,6-tetrakis(trifluoromethyl)-2,5-diphosphatricyclo<3.1.0.0^2,6>hex-3-ene (4), the first isolated analogue of benzvalene containing heteroatoms in its ring system.Compound (4) reacted with dienes or phenyl azide as a dienophile or a dipolarophile.

Full text of DOI:10.1021/jo01311a027

Products guided by the article

Product name:9-phenyl-1,3,4,6-tetrakis(trifluoromethyl)-2,5-diphospha-7,8,9-triazatetracyclo<4.3.0.0^2,4.0^3,5>non-7-ene

Cas No:74930-72-6

R&D Labs maybe for 74930-72-6

Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China

Relevant to this article

Doi:10.1021/jo50017a017
(1953)
Rhenium-to-benzoylpyridine and rhenium-to-bipyridine MLCT excited states of fac-[Re(Cl)(4-benzoylpyridine)₂(CO)₃] and fac-[Re(4-benzoylpyridine)(CO)₃(bpy)]⁺: A time-resolved spectroscopic and spectroelectrochemical study

Doi:10.1021/ic049659m
(2004)
Photoinduced Dithiolation of Fullerene[60] with Dendrimer Disulfide

Doi:10.1246/cl.2003.1124
(2003)
Synthesis and catalytic properties of p-acylthio(phenylacetylene)_n substituted chiral manganese salen complexes

Doi:10.1039/b104103g
(2001)
Reactions of 9-substituted guanines with bromomalondialdehyde in aqueous solution predominantly yield glyoxal-derived adducts.

Doi:10.1039/b405117c
(2004)
Quantitative structure-activity relationships in 2,5-bis(1-aziridinyl)-p-benzoquinone derivatives against leukemia L-1210

Doi:10.1021/jm00191a006
(1979)

Article Doi