Journal of Organometallic Chemistry p. 27 - 38 (1980)
Update date:2022-08-04
Topics:
Herberich, G.E.
Thoennessen, M.
Schmitz, D.
Nine complexes of type ML2 with M = Ni, Pd, Pt and L = X(CH=CH)2BC6H5 (X = (CH3)2C, (CH3)2Si, (CH2)2) are described.The X-ray structural analysis of Ni<(CH3)2Si(CH=CH)2BC6H5>2 and the 1H and 11B NMR spectra demonstrate a sandwich-type bis(η5-divinylborane)metal structure with C2 molecular symmetry.All complexes show exceptional thermal stability as compared to the corresponding bis(1,5-cyclooctadienyl)metal complexes.In the 1H NMR spectra internal rotation of the two ligands with respect to each other is observed for two Pd complexes and the Pt complexes at room temperature.
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Doi:10.1246/cl.1998.817
(1998)Doi:10.1007/BF01435827
(1996)Doi:10.1246/bcsj.53.1769
(1980)Doi:10.1021/ja01543a036
(1958)Doi:10.1021/jo01313a017
(1980)Doi:10.1016/S0022-328X(00)90641-7
(1980)
