A New Reaction of a 7,7-Diethoxybicyclooctan-2-one Derivative. The Formation of the Bicyclooctane Skeleton

DOI: 10.1246/bcsj.53.1177

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1177 - 1178 (1980)

Update date:2022-08-05

Topics:

Authors:

Yanagiya, Mitsutoshi

Tomita, Takamasa

Matsumoto, Takeshi

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Article abstract of DOI:10.1246/bcsj.53.1177

2,2-Diethoxytricyclo<6.4.0.0^1,4>dodecan-5-one was rearranged to 11-ethoxytricyclo<7.2.1.0^1,6>dodec-10-en-12-one under GLC conditions (Thermol-3 on Shimalite, 200 deg C) in an 87 percent yield.

Full text of DOI:10.1246/bcsj.53.1177

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