PHOTOCHEMICAL REACTIONS OF CATIONIC ISOCYANIDE/CARBONYL COMPLEXES OF IRON WITH SELECTED NUCLEOPHILES

DOI: 10.1016/S0022-328X(00)85916-1

Source and publish data:

Journal of Organometallic Chemistry p. 187 - 200 (1980)

Update date:2022-08-04

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Authors:

Johnson, Bryce V.

Steinmetz, Alan L.

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Article abstract of DOI:10.1016/S0022-328X(00)85916-1

Photolysis of <η⁵-C5H5Fe(CO)(CNMe)2>PF6 in the presence of excess nucleophiles resulted in efficient substitution of the carbonyl ligand, generating the new isocyanide complexes <η⁵-C5H5Fe(CNMe)2(L)>PF6 (L = PPh3, AsPh3, SbPh3, pyrid

Full text of DOI:10.1016/S0022-328X(00)85916-1

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Product name:[C₅H₅FeCO(CNCH₃)(As(C₆H₅)3)]⁽¹⁺⁾*PF₆^(1-)=[C₅H₅FeCO(CNCH₃)(As(C₆H₅)3)]PF₆

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