Tetrahedron p. 2909 - 2924 (1996)
Update date:2022-08-05
Topics: Workup and Isolation Coupling Reaction Rearrangement and cyclization
Enders, Dieter
Hecker, Peter
Meyer, Oliver
Coupling of α-chloro enamines as key building blocks with alkenyl lithium compounds lead to the formation of 2-amino-1,3-dienes 6. These cross conjugated enamines constitute important diene components for stereoselective Diels-Alder reactions were prepared in 32-75% overall yield starting from the corresponding amides.
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