A novel approach to 2-amino-1,3-dienes by coupling of α-chloro enamines and alkenyl lithium compounds

DOI: 10.1016/0040-4020(95)01126-9

Source and publish data:

Tetrahedron p. 2909 - 2924 (1996)

Update date:2022-08-05

Topics: Workup and Isolation Coupling Reaction Rearrangement and cyclization

Authors:

Enders, Dieter

Hecker, Peter

Meyer, Oliver

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Article abstract of DOI:10.1016/0040-4020(95)01126-9

Coupling of α-chloro enamines as key building blocks with alkenyl lithium compounds lead to the formation of 2-amino-1,3-dienes 6. These cross conjugated enamines constitute important diene components for stereoselective Diels-Alder reactions were prepared in 32-75% overall yield starting from the corresponding amides.

Full text of DOI:10.1016/0040-4020(95)01126-9

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