A Short Synthesis of 3-Methyl-5-(2,3,6-trimethylphenyl)-1-penten-2-ol, a Sesquiterpene Isolated from Laurencia Nidifaca

DOI: 10.1002/hlca.19800630425

Source and publish data:

Helvetica Chimica Acta p. 967 - 969 (1980)

Update date:2022-08-05

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Authors:

Oppolzer, Wolfgang

Briner, Paul H.

Snowden, Roger L.

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Article abstract of DOI:10.1002/hlca.19800630425

The racemic sesquiterpenoid alcohol 7 was synthesized in four steps (27percent overall yield) from the cyclohexadienone 1.The key steps are the regioselective addition of the pentadienyllithium 2 to 1 and Lewis-acid induced aromatization 4 -> 6.

Full text of DOI:10.1002/hlca.19800630425

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