Journal of Organic Chemistry p. 7797 - 7802 (2015)
Update date:2022-08-02
Topics:
Taniguchi, Nobukazu
Nickel-catalyzed hydroxysulfonylation of alkenes was achieved using sodium sulfinates under air atmosphere. The procedure enabled the selective synthesis of β-hydroxysulfones in good yields and suppressed the formation of β-ketosulfones. On the contrary, sulfonylation of alkynes with sodium sulfonates afforded only β-ketosulfones.
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