Journal of Organic Chemistry p. 5095 - 5100 (1980)
Update date:2022-07-30
Topics:
Kiguchi, Toshiko
Schuppiser, Jean-Luc
Schwaller, Jean-Claude
Streith, Jacques
Starting from 2-chloropyridine 7, a series of 1,2-diazepin-3-ones 16 was prepared by a five-step synthesis.The key intermediates were the bicyclic oxadiazolium salts 10 which led, through a methoxide ion induced ring opening, to the expected 2-methoxypyri
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