Synthesis p. 1680 - 1686 (2004)
Update date:2022-08-05
Topics:
De Buyck, Laurent
Cagnoli, Rita
Ghelfi, Franco
Merighi, Giulia
Mucci, Adele
Pagnoni, Ugo M.
Parsons, Andrew F.
A new and efficient approach to chaetomellic anhydride A has been devised starting from 2,2-dichloropalmitic acid. This involves the atom transfer radical cyclization of an N-alkyl-N-(3-chloro-2-propenyl)amide followed by rearrangement of the resulting trichloro-pyrrolidin-2-one.
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(1980)Doi:10.1002/jhet.5570170313
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