Bulletin of the Chemical Society of Japan p. 177 - 181 (1982)
Update date:2022-08-04
Topics:
Itoh, Osamu
Iwakoshi, Naoki
Saitoh, Toshihide
Katano, Hiroaki
Fujisawa, Yoshiki
et al.
Regio- and stereochemical studies of the solvolyses of various kinds of 2,4-pentanediol derivatives, including 2-acetoxy-4-tosylates, cyclic orthoformates and orthoacetates, have been done and the previously proposed mechanism has been partially revised. The reactions of the proposed intermediate acetoxonium ions with carbanions and with a hydride ion have also been studied.
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