STEREOSELECTIVE SYNTHESIS OF (E)-ALKENYLSILANES FROM ALDEHYDES WITH A REAGENT PREPARED BY CHROMIUM(II) REDUCTION OF Me3SiCHBr2

DOI: 10.1016/S0040-4039(00)95949-5

Source and publish data:

Tetrahedron Letters p. 1443 - 1446 (1987)

Update date:2022-08-04

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Authors:

Takai, Kazuhiko

Kataoka, Yasutaka

Okazoe, Takashi

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)95949-5

Aldehydes are converted to the corresponding (E)-alkenylsilanes with one carbon homologation by means of a gemdichromium reagent prepared by CrCl2 reduction of Me3SiCHBr2 in THF.Transformation of aldehydes into alkenyl sulfides is also achieved with a com

Full text of DOI:10.1016/S0040-4039(00)95949-5

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