A New Method for Stereoselective Piperidine Annulation. Directing the 2-Azonia--Sigmatropic Rearrangement by Irreversible Hydrolysis

DOI: 10.1021/jo01313a051

Source and publish data:

Journal of Organic Chemistry p. 5229 - 5230 (1980)

Update date:2022-08-04

Topics:

Authors:

Overman, Larry E.

Yokomatsu, Tsutomu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01313a051

A new method for stereoselective piperidine annulation is described involving the cyclization and subsequent <3,3>-sigmatropic rearrangement of (5,5-dimethoxypentyl)-3-butenylamines.

Full text of DOI:10.1021/jo01313a051

Products guided by the article

Product name:[(1S,2R,3S)-3-Benzyloxymethyl-2-(3,3-dimethoxy-propyl)-cyclohexyl]-((S)-1-phenyl-but-3-enyl)-amine

Cas No:75420-93-8

R&D Labs maybe for 75420-93-8

CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Chemsigma International Co.,Ltd.

website:http://www.chemsigma.com

Contact:86-025-58748998

Address:Rm.705, 15th Building,Rd.Xinke II
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Win-Win chemical Co.Ltd

website:http://www.win-winchemical.com

Contact:0086-577-64498589

Address:6F, No. 396 Xingping Road, Longwan Industrial Zone, Wenzhou City, Zhejiang, 325000 P.R.China

Relevant to this article

Doubly Bridged S-Heterocyclic Ethylenes via Stereospecific <2,3> Sigmatropic Rearrangement. Avenue to Short-Bridged Betweenanenes

Doi:10.1021/jo00316a002
(1981)
Long-chain formoterol analogues: An investigation into the effect of increasing amino-substituent chain length on the β₂-adrenoceptor activity

Doi:10.1016/j.bmcl.2004.06.086
(2004)
Facile and efficient synthesis of ido-heptulosan via a strategy derived from Mo(VI)-catalysed reactions

Doi:10.1055/s-2001-12773
(2001)
Design, synthesis, and biological evaluation of combretabenzodiazepines: A novel class of anti-tubulin agents

Doi:10.1021/jm5016389
(2015)
Rapid, microwave accelerated synthesis of [1,2,4]triazolo[3,4-b][1,3,4]oxadiazoles from 4-acylamino-1,2,4-triazoles

Doi:10.1016/j.tetlet.2016.07.082
(2016)
ORGANIC CHEMISTRY OF SUBVALENT TRANSITION METAL COMPLEXES XI. OXIDATIVE ADDITIONS OF NICKEL(0) COMPLEXES TO CARBON-CARBON BONDS IN ALKYNES: NICKELIRENES AND NICKELOLES AS CATALYTIC CARRIERS IN THE OLIGOMERIZATION OF ALKYNES

Doi:10.1016/0022-328X(86)80327-8
(1986)

Article Doi