Angewandte Chemie - International Edition p. 11870 - 11874 (2017)
Update date:2022-08-02
Topics:
Chierchia, Matteo
Law, Chunyin
Morken, James P.
Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C?C bond forming reactions.
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