Synthesis of 5-isothiocyanato-1,10-phenanthroline

Article abstract of DOI:10.1134/S1070428006040129

Reduction of 5-nitro-1,10-phenanthroline with hydrogen over Pd/C, followed by the treatment of 1,10-phenanthrolin-5-amine with thiophosgene in the presence of sodium acetate, gave 5-isothiocyanato-1,10-phenanthroline which is a thermally stable highly reactive ligand capable of quantitatively forming covalently bonded nanohybrid structures in a system transition metal complex-silica under mild conditions. Pleiades Publishing, Inc., 2006.

Full text of DOI:10.1134/S1070428006040129

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