Tetrahedron p. 881 - 888 (1993)
Update date:2022-08-04
Topics:
Maas
Werle
Alt
Mayer
The polymeric complex [Ru2(CO)4(μ-OAc)2](n) is the first Ru(I) catalyst that efficiently catalyzes cyclopropanation of alkenes with diazoacetic esters. The related dinuclear catalyst Ru2(CO)4(μ-OAc)2(MeCN)2 shows a similar performance only for cyclopropanation of monosubstituted alkenes.
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