Polymeric dicarbonyl ruthenium(I) acetate - An efficient catalyst for alkene cyclopropanation with diazoacetates

DOI: 10.1016/S0040-4020(01)80330-6

Source and publish data:

Tetrahedron p. 881 - 888 (1993)

Update date:2022-08-04

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Authors:

Maas Maas

Werle Werle

Alt Alt

Mayer Mayer

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Article abstract of DOI:10.1016/S0040-4020(01)80330-6

The polymeric complex [Ru₂(CO)₄(μ-OAc)₂](n) is the first Ru(I) catalyst that efficiently catalyzes cyclopropanation of alkenes with diazoacetic esters. The related dinuclear catalyst Ru₂(CO)₄(μ-OAc)₂(MeCN)₂ shows a similar performance only for cyclopropanation of monosubstituted alkenes.

Full text of DOI:10.1016/S0040-4020(01)80330-6

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