Tetrahedron p. 1565 - 1569 (1980)
Update date:2022-08-03
Topics:
Sasaki, Tadashi
Eguchi, Shoji
Tanaka, Yumo
Thermal decomposition of N(phenylsulfonyl)-benzohydrazonoyl chloride (1) in refluxing toluene generated N-phenylsulfonylbenzonitrilimine (2) which gave 1,3-dipolar cycloadducts with ethyl (4a) and methyl acrylate (4b), acrylonitrile (4c), styrene (4d), norbornene (4e), and norbornadiene (4f). The reactions with 4a-d, 2 afforded regiospecifically 5-R substituted pyrazolines 5a-d in lower yields. The raction of 2 with 4e gave only exo adduct 5e, while the reaction with 4f gave both exo- (5fx) and endo adducts (5fn) as well as their retro-Diels-Alder product 6.
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