INSERTION D'ALLENES. VII. SYNTHESE DE COMPLEXES (η4-HETERODIENE)FER TRICARBONYL A PARTIR D'ALLENES

DOI: 10.1016/S0022-328X(00)96193-X

Source and publish data:

Journal of Organometallic Chemistry p. 357 - 366 (1980)

Update date:2022-08-03

Topics:

Authors:

Roustan, J. L.

Guinot, A.

Cadiot, P.

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Article abstract of DOI:10.1016/S0022-328X(00)96193-X

η⁴-Hydroxytrimethylenemethane-iron complexes are obtained by protonation of complex anions.They isomerise easily into a mixture of isomeric η⁴-heterodieneiron tricarbonyl complexes which have been separated.This demonstrates that such complexes are now available starting from allenes, alkyl halides and sodium tetracarbonyl ferrate.

Full text of DOI:10.1016/S0022-328X(00)96193-X

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