Journal of Organometallic Chemistry p. 83 - 92 (1995)
Update date:2022-08-04
Topics:
Kondo, Teruyuki
Kajiya, Satoshi
Tantayanon, Supawan
Watanabe, Yoshihisa
The following ruthenium-catalyzed novel transformations of alkyl formates have been developed: (1) selective decarbonylation of alkyl formates to the corresponding alcohols; (2) alkylation of arenes and alkenes using alkyl formates as an alkylating reagent via decarboxylation.Also the ruthenium-catalyzed addition of alcohols to alkenes has been developed as an appendant reaction, providing an effective method for the protection of alcohols.Keywords: Ruthenium; Catalysis; Alkyl; Arene; Alkene; Alcohol
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