Journal of the Chemical Society. Perkin transactions I p. 2200 - 2204 (1980)
Update date:2022-08-04
Topics:
McNab, Hamish
Flash vacuum pyrolysis of the title compounds at 600 deg C gives quinoxalines and arylamines, together with small quantities of nitriles, diarylamines, azobenzenes, and formamidines.The mechanism involves homolytic cleavage of the N-N bond to generate a conjugated iminyl radical, which can either cyclise to a quinoxaline, or fragment to simpler radicals which lead to the minor products by coupling reactions.
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Doi:10.1021/acs.joc.9b03006
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(1980)Doi:10.1021/jo01279a021
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(1981)
