Electrophilic reactions of DMAD with a cyclic dienamine: Solvent influence upon the competitive formation of [4+2]-,[2+2]- and michael type adducts

DOI: 10.1016/S0040-4039(01)83935-6

Source and publish data:

Tetrahedron Letters p. 1145 - 1148 (1980)

Update date:2022-08-04

Topics:

Authors:

Eberbach, Wolfgang

Claude Carre, Jean

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Article abstract of DOI:10.1016/S0040-4039(01)83935-6

The reaction course of DMAD with dihydroazepine 3 depends strongly on the solvent: under appropriate conditions either 4, 5 or 6(E) is formed as the exclusive addition product.

Full text of DOI:10.1016/S0040-4039(01)83935-6

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