HEXAMETHYLSILIRANE. II. RING-OPENING REACTIONS WITH SOME SIMPLE REAGENTS

DOI: 10.1016/S0022-328X(00)86821-7

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 192 (1982)

Update date:2022-08-05

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Authors:

Seyferth, Dietmar

Annarelli, Dennis C.

Shannon, Mark L.

Escudie, Jean

Duncan, Don P.

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Article abstract of DOI:10.1016/S0022-328X(00)86821-7

Ring-opening reactions formally of the type occur on reaction of hexamethylsilirane with water, alcohols, ammonia, amines, HCl and carboxylic acids and germanium and tin hydrides.More complicated ring opening reactions are observed with halogens, tetrahalomethanes and molecular oxygen.The oxidation and protolysis (H2O, ROH, HCl, RCO2H, NH3, amines) reactions of hexamethylsilirane are exothermic at room temperature.

Full text of DOI:10.1016/S0022-328X(00)86821-7

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