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The Synthesis, Properties, and the Crystal and Molecular Structures of Five-co-ordinate Copper(I) and Silver(I) Complexes of a Quinquedentate Macrocyclic Ligand having an 'N3S2' Donor Set

DOI: 10.1039/DT9800002020

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2020 - 2027 (1980)

Update date:2022-08-03

Topics:

Authors:

Drew, Michael G.B.Drew, Michael G.B.

Cairns, ColinCairns, Colin

McFall, Stephen G.McFall, Stephen G.

Nelson, S. MartinNelson, S. Martin

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Article abstract of DOI:10.1039/DT9800002020

The 17-membered macrocyclic ligand L1 containing the 'N2S3' donor set has been synthesised by the template action of silver(I) salts on the cyclic Schiff-base condensation of 2,6-diacetyl-pyridine with 1,10-diamine-4,7-dithiadecane. The copper(II) ion was ineffective as a template for the synthesis.However, copper(II) complexes of L1 could be obtained from 1>(1+) via metal exchange (transmetallation).Sodium tetraphenylborate is a reducing agent for IIL1>(2+), affording IL1>(1+) in good yield.Possible mechanisms for the reducing action of (1-) are discussed.Hydrogenation of 1>(1+) salts using Na give the free reduced macrocycle RL1 (i.e.L1 + 4H) from which a new range of macrocyclic complexes may be obtained.Infrared and electronic spectra of the silver(I) and copper(I) complexes of L1 are reported.The copper(I) complexes are unreactive to both O2 and CO.Crystals of 1> are orthorhombic with a = 6.844(7), b = 12.361(11), c = 24.072(21) Angstroem, Z = 4, and space group P212121.Crystals of 1> are monoclinic with a = 13.132(11), b = 25.001(12), c = 12.479(12) Angstroem, β = 105.7(1) deg, Z = 4, and space group P21/c.The two structures were solved by Patterson and Fourier methods from 927 and 2621 reflections above background measured by diffractometer and refined by full-matrix least squares to R 0.077 and 0.071 respectively.While the co-ordination geometry of both complexes is a distorted trigonal bipyramid there are marked differences in the macrocycle conformations in the two cases and, for the copper(I) complex, in the metal-nitrogen bond lengths.These are discussed in relation to the sizes of the two metal ions and of the macrocycle hole size.

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