Molecular Organization by Hydrogen Bonding: Juxtaposition of Remote Double Bonds for Photocyclization in a 2-Pyridone Dimer

DOI: 10.1021/jo00316a027

Source and publish data:

Journal of Organic Chemistry p. 619 - 624 (1981)

Update date:2022-08-02

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Authors:

Beak, Peter

Zeigler, John M.

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Article abstract of DOI:10.1021/jo00316a027

Irradiation of the hydrogen bonded dimer of 3-<7-(cinnamoyloxy)heptyl>-6-<6-(cinnamoyloxy)hexyl>-2-pyridone (1) provides the δ-truxinic acid ester 3 and the β-truxinic acid ester 4, respectively.The photocyclization occurs via a 25-membered ring in yields

Full text of DOI:10.1021/jo00316a027

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