Inorganic Chemistry p. 1318 - 1321 (1982)
Update date:2022-08-05
Topics:
Girolami, Gregory S.
Andersen, Richard A.
The X-ray crystal structure of the orange-yellow isomer of Mo2(O2CCF3)4(PMePh2) 2 confirms that it possesses a class I (axial) structure as previously deduced spectroscopically. Accordingly, PMePh2 is capable of forming both class I and class II (equatorial) adducts with Mo2(O2CCF3)4. NMR studies show that an equilibrium between the two isomers is established in solution. Crystal data: space group P21/c; a = 9.923 (1) ?, b = 22.517 (2) ?, c = 18.735 (3) ?, β = 99.18 (1)°; V= 4132 (2) ?3; Z = 4; R = 4.43%, Rw = 6.63%; Mo-Mo = 2.128 (1)?, Mo-P = 2.988 = 0.024 ?, Mo-Mo-P = 166.15 = 0.16°.
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Doi:10.1039/jr9590002654
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(1981)
