FUNCTIONALLY SUBSTITUTED ORGANOTIN COMPOUNDS. I. PREPARATION AND HYDROSTANNATION OF STANNYLATED ALLYLIC ALCOHOLS AND RELATED COMPOUNDS

Article abstract of DOI:10.1016/S0022-328X(00)84521-0

Hydrostannation of 1-alkynols leads to the formation of the corresponding triorganostannylalkenols in good yields.The main product is the trans-isomer, while cis- and α-products are formed in lower yields.In some cases the stannyl alkenols can be further