5-(Arylamino)-1,2,3-triazoles and 5-Amino-1-aryl-1,2,3-triazoles from 3-(Cyanomethyl)triazenes

DOI: 10.1021/jo00318a006

Source and publish data:

Journal of Organic Chemistry p. 856 - 859 (1981)

Update date:2022-08-02

Topics:

Authors:

Baines, Kim M.

Rourke, Timothy W.

Vaughan, Keith

Hooper, Donald L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00318a006

1-Aryl-3-(cyanomethyl)triazenes (1) cyclize in aprotic media, with Lewis base catalysis, to 5-amino-1-aryl-1,2,3-triazoles (2), whereas in protic media cyclization, followed by Dimroth rearrangement, affords the isomeric 5-(arylamino)-1,2,3-triazoles (3).

Full text of DOI:10.1021/jo00318a006

Products guided by the article

Product name:1--3-(cyanomethyl)triazene

Cas No:76109-70-1

R&D Labs maybe for 76109-70-1

Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Jiangxi Hito Chemical Co., Ltd.

Contact:+86-792-3170318

Address:No. 6, Tianhong Ave., Xinghuo Industry Park, Yongxiu, Jiujiang, Jiangxi, China
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA

Relevant to this article

Synthesis, antimalarial, antileishmanial, antimicrobial, cytotoxicity, and methemoglobin (MetHB) formation activities of new 8-quinolinamines

Doi:10.1016/j.bmc.2006.10.036
(2007)
Identification and stereochemistry of (2S, 4S, 5R)- and (2R, 4S, 5R)-2,3,4-trimethyl-5-phenyloxazolidine, degradation products of ephedrine

Doi:10.1016/0040-4020(77)80157-9
(1977)
Mechanistic studies on counter-ionic effects of camphorsulfonate-based ionic liquids on kinetics, thermodynamics and stereoselectivity of β-amino carbonyl compounds

Doi:10.1016/j.molliq.2020.114370
(2020)
Quantitative structure-activity relationships of anticonvulsant aralkyl and alkyl carbamates

Doi:10.1248/cpb.33.2403
(1985)
2-Substituted bicyclo[3.2.1]oct-2-en-8-ones by carbonylation of cycloheptadiene-derived iron carbonyl complexes bearing alkyl-alkyl subunits

Doi:10.1055/s-1995-3940
(1995)
Spiroannelation via Intramolecular Ketocarbenoid Addition. Stereocontrolled Synthesis of (-)-Acorenone B and (+/-)-α-Chamigrene

Doi:10.1021/ja00397a040
(1981)

Article Doi