Tetrahedron Letters p. 3051 - 3054 (1980)
Update date:2022-08-05
Topics:
Bats, J.-P.
Moulines, J.
Picard, P.
Leclerq, D.
The transposition of oxirane-ethanols, through alkoxytin compounds, into oxetane-2-methanols and/or oxolan-3-ols (tetrahydrofuran-3-ols) is dependent upon the oxirane configuration.Cis configuration is more suitable for the formation of the smallest ring.Steric hindrance is not sufficient enough to explain the results.
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(1948)
