Tetrahedron Letters p. 2577 - 2580 (1980)
Update date:2022-09-26
Topics:
Michel, P.
O'Donnell, M.
Biname, R.
Hesbain-Frisque, A.M.
Ghosez, L.
et al.
Adducts of alkyl(phenylthio)ketenes to cyclopentadiene are cleaved with KOH-t-BuOK with retention of configuration at three centers.This observation broadens the synthetic potential of the method of vicinal alkylation of olefins.This method has been used for the vicinal addition of
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Doi:10.1007/BF00471876
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(2016)Doi:10.1039/c7ta05534j
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