PREPARATIONS OF 2-epi-FORTIMICINS A FROM 2-epi-FORTIMICIN B BY INTRAMOLECULAR BASE-CATALYZED 2-O-ACYLATION OF 1,2',6'-TRI-N-BENZYLOXYCARBONYL-2-EPI-FORTIMICIN B

DOI: 10.1016/S0008-6215(00)80393-6

Source and publish data:

Carbohydrate Research p. 207 - 218 (1981)

Update date:2022-08-04

Topics: Intramolecular Base-catalyzed Preparations 2-epi-FORTIMICIN B

Authors:

Tadanier, Jack

Hallas, Robert

Martin, Jerry R.

Cirovic, Momir

Stanaszek, Ruth S.

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Article abstract of DOI:10.1016/S0008-6215(00)80393-6

Preparation of 2-epi-fortimicin A (4) from 2-epi-fortimicin B (3) are described.In contrast to the previously reported, selective 4-N-acylation of 1,2',6'-tri-N-benzyloxycarbonylfortimicin B (8) with N-(N-benzyloxycarbonylglycyloxy)succinimide, 1,2',6'-tr

Full text of DOI:10.1016/S0008-6215(00)80393-6

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