LIGAND REDISTRIBUTION AND CARBONYL INSERTION: THE EFFECT OF COMPETITIVE ?-DONATION

DOI: 10.1016/S0022-328X(00)87924-3

Source and publish data:

Journal of Organometallic Chemistry p. 389 - 398 (1980)

Update date:2022-08-05

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Authors:

Marsella, John A.

Moloy, Kenneth G.

Caulton, Kenneth G.

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Article abstract of DOI:10.1016/S0022-328X(00)87924-3

Electron deficient CpTiCl3 reacts with the bis-alkoxide to produce the diolato dimer (CpTiCl2)OCMe2CMe2O(TiCl2Cp).CpTiCl3 reacts with Cp4Ti4Cl4(μ₂-O)4, which also has two oxo ligands on each titanium atom, to produce 2O.These

Full text of DOI:10.1016/S0022-328X(00)87924-3

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