Oxy-Cope Rearrangement Route to Bridgehead Olefins

DOI: 10.1021/jo00323a052

Source and publish data:

Journal of Organic Chemistry p. 2199 - 2200 (1981)

Update date:2022-07-30

Topics:

Authors:

Levine, Samuel G.

McDaniel, Roger L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00323a052

Bicyclic bridgehead olefins, with a carbonyl group included in the largest bridge, may be synthesized by oxy-Cope rearrangement of easily accessible spirocyclic precursors.

Full text of DOI:10.1021/jo00323a052

Products guided by the article

Product name:spiro[5.5]undec-7-en-1-one

Cas No:77080-00-3

R&D Labs maybe for 77080-00-3

FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
Phantom-pharma

Contact:

Address:
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China

Relevant to this article

Acylation and Cyclization of N-Hydroxyisoureas by Phenyl Isocyanate

Doi:10.1002/ardp.19813140104
(1981)
A Versatile Reagent and Method for Direct Aliphatic Sulfonylation

Doi:10.1002/adsc.201800071
(2018)
Chemistry of the Energy-Rich m-Quinomethane System. Formal (3+2) Cycloaddition to Olefins via a Singlet Intermediate

Doi:10.1021/ja00382a040
(1982)
Teikaside A, a pregnane glycoside of Trachelospermum asiaticum

Doi:10.1248/cpb.29.416
(1981)
Cyclization of acetylenic amides using a cationic rhodium(I) complex

Doi:10.1071/CH04032
(2004)
PIFA-Mediated Dearomatizative Spirocyclization of Phenolic Biarylic Ketones via Oxidation and C-C Bond Cleavage

Doi:10.1021/acs.joc.0c00971
(2020)

Article Doi