Tetrahedron Letters p. 3787 - 3790 (1980)
Update date:2022-08-02
Topics:
Tamaru, Y.
Suzuki, R.
Kagotani, M.
Yoshida, Z.
Toluenesulfinate serves as a cocatalyst for the selective formation of α-hydroxy α-octa-2,7-dienyl ketones (2, the products of C-C bond formation) in the reaction of palladium catalyzed dimerization of 1,3-butadiene with acyloins, while the same reaction using triphenylphosphine, instead of toluenesulfinate, as a cocatalyst provides a mixture of 2 and 2-oxy octa-2',7'-dienyl ethers (3, the products of C-O bond formation).
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Doi:10.1016/S0040-4039(00)77862-2
(1980)Doi:10.1021/ja00395a085
(1981)Doi:10.1039/DT9810000034
(1981)Doi:10.1021/acs.orglett.7b01218
(2017)Doi:10.1021/jo00326a002
(1981)Doi:10.1039/P19810002282
(1981)
