Conversion of vinylsilanes to vinyl halides with xenon difluoride and metal halides. A versatile new route to 5-(2-halovinyl)pyrimidine nucleosides

DOI: 10.1016/S0040-4039(00)97919-X

Source and publish data:

Tetrahedron Letters p. 5633 - 5636 (1990)

Update date:2022-08-02

Topics:

Authors:

Robins Robins

Manfredini

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97919-X

Addition of a protected 5-(2-trimethylsilylvinyl)uracil nucleoside to suspensions of xenon difluoride and alkali metal halides in benzene (or other solvents) resulted in rapid formation of the corresponding 5-(2-halovinyl)uracil products (E-isomer predominating).

Full text of DOI:10.1016/S0040-4039(00)97919-X

Products guided by the article

Product name:1-beta-arabinofuranosyl-5-(2-chlorovinyl)uracil

Cas No:77181-70-5

R&D Labs maybe for 77181-70-5

shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Shanghai doly chemical Co.,Ltd

Contact:+86-21-34716221

Address:No.328,WuHe Roard,MinHang,ShangHai China
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road

Relevant to this article

2-Aroylindoles and 2-aroylbenzofurans with N-hydroxyacrylamide substructures as a novel series of rationally designed histone deacetylase inhibitors

Doi:10.1021/jm0703136
(2007)
Use of the Suzuki reaction for the synthesis of aryl-substituted heterocycles as corticotropin-releasing hormone (CRH) antagonists

Doi:10.1016/S0960-894X(99)00133-X
(1999)
Sequential free radical reactions with xanthates: Cyclopentane ring annulation

Doi:10.1055/s-1998-1946
(1998)
Design, synthesis, and characterization of 1,3,5-Tri(1 H-benzo[d]imidazol-2-yl)benzene-based fluorescent supramolecular columnar liquid crystals with a broad mesomorphic range

Doi:10.1021/jo5016954
(2014)
Preparation, coordination properties and catalytic use of 1′-(diphenylphosphanyl)-1-ferrocenecarboxamides bearing 2-hydroxyethyl pendant groups

Doi:10.1016/j.jorganchem.2009.04.007
(2009)
Silver catalyzed zinc Barbier reaction of benzylic halides in water

Doi:10.1016/S0040-4039(98)02199-6
(1998)

Article Doi