SYNTHESES OF DICTYOPTERENE B (HORMOSIRENE) AND ITS ENANTIOMER VIA ASYMMETRIC ScN' REACTIONS

DOI: 10.1016/S0040-4039(00)98287-X

Source and publish data:

Tetrahedron Letters p. 3319 - 3322 (1985)

Update date:2022-08-03

Topics:

Authors:

Dorsch, Dieter

Kunz, Erika

Helmchen, Guenter

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Article abstract of DOI:10.1016/S0040-4039(00)98287-X

Stereocontrolled syntheses of dictyopterene B (hormosirene) (1) and its enantiomer (ent-1) are reported.Key steps are highly stereoselective S_cN' reactions of esters of alkohols 2 and 5 derived from (+)-camphor.

Full text of DOI:10.1016/S0040-4039(00)98287-X

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