Asymmetric hydroformylations of sulfur-containing olefins catalyzed by BINAPHOS-Rh(I) complexes

DOI: 10.1016/0957-4166(95)00339-Q

Source and publish data:

Tetrahedron Asymmetry p. 2583 - 2591 (1995)

Update date:2022-09-26

Topics:

Authors:

Nanno Nanno

Sakai Sakai

Nozaki Nozaki

Takaya Takaya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(95)00339-Q

Asymmetric hydroformylations of vinyl sulfides, allyl sulfides, and allyl sulfones catalyzed by (R,S)-BINAPHOS/Rh(acac)(CO₂) afforded the corresponding branched oxo aldehydes as major products in 60-80% ee. Use of bulkier substituents on the sulfur in vinyl sulfides gave the branched oxo-aldehydes in higher regio- and enantioselectivities.

Full text of DOI:10.1016/0957-4166(95)00339-Q

Products guided by the article

Product name:3-(tert-butylsulfanyl)propanal

Cas No:77275-25-3

R&D Labs maybe for 77275-25-3

Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,
Zhejiang Quzhou Jiancheng Silicone Co., Ltd.(Shanghai Jiancheng Industial and Trade Co, Ltd)

Contact:18957018777 +86-570-3888777

Address:The company production base address： Quzhou City, Zhejiang Province high-tech industrial park Nianhua Road 37
ZHEJIANG NHU COMPANY LTD.

Contact:86-575-86132822，86-575-86085355

Address:No.418 Dadao West Road,Qixing Street,Xinchang, Zhejiang Province, China.
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China

Relevant to this article

Bimetallic sandwiches based upon phosphole ligands

Doi:10.1021/ic50223a022
(1981)
Synthesis and reactions of a binuclear cobalt bridging methylene (μ-CH₂) complex. Conversion to μ-CH₂ Rh/Co and Rh/Rh complexes and methylene transfer to ethylene involving activation by a second metal complex

Doi:10.1021/ja00399a092
(1981)
Activation of the G-protein-coupled receptor 119: A conformation-base hypothesis for understanding agonist response

Doi:10.1021/jm200003p
(2011)
Dilithium Diphenylmethanediide; Generation, Redox Relationship with Lithium Chlorodiphenylmethanide, Implication with Regard to Aggregation

Doi:10.1039/C39910000438
(1991)
Structure-activity relationship of phosmidosine: Importance of the 7,8-dihydro-8-oxoadenosine residue for antitumor activity

Doi:10.1016/j.bmc.2004.07.021
(2004)
Methane-producing hydrogenolysis of (η⁵-cyclopentadienyl)(triphenylphosphine)dimethylcobalt(III). An autocatalytic mechanism involving a binuclear metal dihydride/metal dialkyl reaction as a critical step

Doi:10.1021/ja00399a091
(1981)

Article Doi