Asymmetric hydroformylations of sulfur-containing olefins catalyzed by BINAPHOS-Rh(I) complexes

DOI: 10.1016/0957-4166(95)00339-Q

Source and publish data:

Tetrahedron Asymmetry p. 2583 - 2591 (1995)

Update date:2022-09-26

Topics:

Authors:

Nanno Nanno

Sakai Sakai

Nozaki Nozaki

Takaya Takaya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(95)00339-Q

Asymmetric hydroformylations of vinyl sulfides, allyl sulfides, and allyl sulfones catalyzed by (R,S)-BINAPHOS/Rh(acac)(CO₂) afforded the corresponding branched oxo aldehydes as major products in 60-80% ee. Use of bulkier substituents on the sulfur in vinyl sulfides gave the branched oxo-aldehydes in higher regio- and enantioselectivities.

Full text of DOI:10.1016/0957-4166(95)00339-Q

Products guided by the article

Product name:3-(tert-butylsulfanyl)propanal

Cas No:77275-25-3

R&D Labs maybe for 77275-25-3

Hawks Chemical

Contact:+44 (0)161 367 9441

Address:
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China

Relevant to this article

Bimetallic sandwiches based upon phosphole ligands

Doi:10.1021/ic50223a022
(1981)
Synthesis and reactions of a binuclear cobalt bridging methylene (μ-CH₂) complex. Conversion to μ-CH₂ Rh/Co and Rh/Rh complexes and methylene transfer to ethylene involving activation by a second metal complex

Doi:10.1021/ja00399a092
(1981)
Activation of the G-protein-coupled receptor 119: A conformation-base hypothesis for understanding agonist response

Doi:10.1021/jm200003p
(2011)
Dilithium Diphenylmethanediide; Generation, Redox Relationship with Lithium Chlorodiphenylmethanide, Implication with Regard to Aggregation

Doi:10.1039/C39910000438
(1991)
Structure-activity relationship of phosmidosine: Importance of the 7,8-dihydro-8-oxoadenosine residue for antitumor activity

Doi:10.1016/j.bmc.2004.07.021
(2004)
Methane-producing hydrogenolysis of (η⁵-cyclopentadienyl)(triphenylphosphine)dimethylcobalt(III). An autocatalytic mechanism involving a binuclear metal dihydride/metal dialkyl reaction as a critical step

Doi:10.1021/ja00399a091
(1981)

Article Doi