Asymmetric hydroformylations of sulfur-containing olefins catalyzed by BINAPHOS-Rh(I) complexes

DOI: 10.1016/0957-4166(95)00339-Q

Source and publish data:

Tetrahedron Asymmetry p. 2583 - 2591 (1995)

Update date:2022-09-26

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Authors:

Nanno Nanno

Sakai Sakai

Nozaki Nozaki

Takaya Takaya

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Article abstract of DOI:10.1016/0957-4166(95)00339-Q

Asymmetric hydroformylations of vinyl sulfides, allyl sulfides, and allyl sulfones catalyzed by (R,S)-BINAPHOS/Rh(acac)(CO₂) afforded the corresponding branched oxo aldehydes as major products in 60-80% ee. Use of bulkier substituents on the sulfur in vinyl sulfides gave the branched oxo-aldehydes in higher regio- and enantioselectivities.

Full text of DOI:10.1016/0957-4166(95)00339-Q

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