Synthetic Photochemistry. XXI. The Sensitized Photooxygenation of Calarene. A Facile Hock Cleavage of an Allylhydroperoxide and Structure Revision for Aristolenols

DOI: 10.1246/bcsj.53.3721

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3721 - 3722 (1980)

Update date:2022-08-04

Topics:

Authors:

Takeshita, Hitoshi

Shimooda, Isao

Hatsui, Toshihide

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.53.3721

An allylic hydroperoxide formed by the sensitized photooxidation of calarene causes a Hock cleavage.A revised stereochemistry of an aristolenol is given on the basis of the direction of oxygenation.

Full text of DOI:10.1246/bcsj.53.3721

Products guided by the article

Product name:1,8,9,10-Tetradehydroaristolan

Cas No:77381-77-2

R&D Labs maybe for 77381-77-2

Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Changzhou Sunsheng Chem Co., Ltd

Contact:+1-(989)-854-0648

Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China

Relevant to this article

Functional mimicry of carboxypeptidase A by a combination of transition state stabilization and a defined orientation of catalytic moieties in molecularly imprinted polymers

Doi:10.1021/ja8012648
(2008)
Doi:10.1007/BF00913011
(1978)
The synthesis and evaluation of thymoquinone analogues as anti-ovarian cancer and antimalarial agents

Doi:10.1016/j.bmcl.2018.02.051
(2018)
Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Doi:10.1002/chem.202002646
(2020)
Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Doi:10.1246/bcsj.80.371
(2007)
Retention of configuration and regiochemistry in allylic alkylations via the memory effect

Doi:10.1021/om0306224
(2004)

Article Doi