Synthetic Photochemistry. XXI. The Sensitized Photooxygenation of Calarene. A Facile Hock Cleavage of an Allylhydroperoxide and Structure Revision for Aristolenols

DOI: 10.1246/bcsj.53.3721

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3721 - 3722 (1980)

Update date:2022-08-04

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Authors:

Takeshita, Hitoshi

Shimooda, Isao

Hatsui, Toshihide

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Article abstract of DOI:10.1246/bcsj.53.3721

An allylic hydroperoxide formed by the sensitized photooxidation of calarene causes a Hock cleavage.A revised stereochemistry of an aristolenol is given on the basis of the direction of oxygenation.

Full text of DOI:10.1246/bcsj.53.3721

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