Synthetic Photochemistry. XXI. The Sensitized Photooxygenation of Calarene. A Facile Hock Cleavage of an Allylhydroperoxide and Structure Revision for Aristolenols

DOI: 10.1246/bcsj.53.3721

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3721 - 3722 (1980)

Update date:2022-08-04

Topics:

Authors:

Takeshita, Hitoshi

Shimooda, Isao

Hatsui, Toshihide

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.53.3721

An allylic hydroperoxide formed by the sensitized photooxidation of calarene causes a Hock cleavage.A revised stereochemistry of an aristolenol is given on the basis of the direction of oxygenation.

Full text of DOI:10.1246/bcsj.53.3721

Products guided by the article

Product name:1,8,9,10-Tetradehydroaristolan

Cas No:77381-77-2

R&D Labs maybe for 77381-77-2

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Goldwills Pharmaceuticals Co., Ltd.

Contact:0916-2237889 13991621155

Address:North Suburb of Hanzhong city, Shaanxi Province
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA

Relevant to this article

Functional mimicry of carboxypeptidase A by a combination of transition state stabilization and a defined orientation of catalytic moieties in molecularly imprinted polymers

Doi:10.1021/ja8012648
(2008)
Doi:10.1007/BF00913011
(1978)
The synthesis and evaluation of thymoquinone analogues as anti-ovarian cancer and antimalarial agents

Doi:10.1016/j.bmcl.2018.02.051
(2018)
Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Doi:10.1002/chem.202002646
(2020)
Orientation and substituent effects on the properties of the diacetylene-group connected octaethylporphyrin-dihexylbithiophene derivatives (OEP-DHBTh-X) carrying electron-withdrawing groups

Doi:10.1246/bcsj.80.371
(2007)
Retention of configuration and regiochemistry in allylic alkylations via the memory effect

Doi:10.1021/om0306224
(2004)

Article Doi