Chemistry of Heterocyclic Compounds p. 480 - 483 (1981)
Update date:2022-08-05
Topics:
Kotovskaya
Mokrushina
Postovskii
Polyakova
Two parallel reactions, viz., cyclization of 2-nitro-3-azidopyridine to pyrido-[2,3-c]furoxan, which is aminated in the 6 position of the pyridine ring with opening of the furoxan ring, and reduction of the azido group to form 2-nitro-3-aminopyridine, occur in the reaction of 2-nitro-3-azidopyridine with amines. It was established that pyrido[2,3-c]furoxan reacts with amines in aqueous media in the 1-oxide form.
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Doi:10.1002/jhet.5570170824
(1980)Doi:10.1021/ja00384a021
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(1983)
