Trapping of free-radicals in the oxidation of ethers, aldehydes and alkanes by dimethyldioxirane

DOI: 10.1016/0040-4039(95)00106-M

Source and publish data:

Tetrahedron Letters p. 1895 - 1898 (1995)

Update date:2022-08-02

Topics:

Authors:

Minisci, Francesco

Zhao, Lihua

Fontana, Francesca

Bravo, Anna

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Article abstract of DOI:10.1016/0040-4039(95)00106-M

Alkyl, α-oxyalkyl and acyl radical intermediates in the oxidation of alkanes, ethers and aldehydes by dimethyldioxirane are trapped by protonated quinolines and a free-radical chain is suggested for the α-acetoxylation of ketones.

Full text of DOI:10.1016/0040-4039(95)00106-M

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