Synthesis and Stereomutation of Optically Active α-Cyanosulphoxides

DOI: 10.1039/P19810000614

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 614 - 617 (1981)

Update date:2022-08-02

Topics:

Authors:

Annunziata, Rita

Cinquini, Mauro

Colonna, Stefano

Cozzi, Franco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810000614

Reaction of (-)-menthyl (S)-toluene-p-sulphinate with nitriles and lithium NN-di-isopropylamide (LDA) in 1:1:1 and 1:2:1 ratios affords optically active α-cyano- and α-cyano-β-imino-sulphoxides, respectively. α-Cyanobenzyl sulphoxide racemizes through a h

Full text of DOI:10.1039/P19810000614

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Phenyl-((R)-toluene-4-sulfinyl)-acetonitrile

Cas No:77597-93-4

R&D Labs maybe for 77597-93-4

Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section

Relevant to this article

Efficient and Clean Nickel Catalyzed α-Allylation Reaction of Nitriles

Doi:10.1002/adsc.202001338
(2021)
Ni(ii) source as a pre-catalyst for the cross-coupling of benzylic pivalates with arylboronic acids: Facile access to tri- and diarylmethanes

Doi:10.1039/c4ra16452k
(2015)
Dynamic Motion of Organic Ligands in Polar Layered Cobalt Phosphonates

Doi:10.1002/chem.201801301
(2018)
Chemoenzymatic synthesis of 7-deaza cyclic adenosine 5′-diphosphate ribose analogues, membrane-permeant modulators of intracellular calcium release

Doi:10.1021/jo071236p
(2008)
New regioselective synthesis and biological activity of substituted 1H-[1,2,4]triazolo[3,4-c][1,2,4]triazoles

Doi:10.1002/jccs.200400054
(2004)
Highly regioselective ring opening of epoxides using NaN₃: A short and efficient synthesis of (-)-cytoxazone

Doi:10.1016/j.tetlet.2004.07.157
(2004)

Article Doi