Synthesis and Stereomutation of Optically Active α-Cyanosulphoxides

DOI: 10.1039/P19810000614

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 614 - 617 (1981)

Update date:2022-08-02

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Authors:

Annunziata, Rita

Cinquini, Mauro

Colonna, Stefano

Cozzi, Franco

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Article abstract of DOI:10.1039/P19810000614

Reaction of (-)-menthyl (S)-toluene-p-sulphinate with nitriles and lithium NN-di-isopropylamide (LDA) in 1:1:1 and 1:2:1 ratios affords optically active α-cyano- and α-cyano-β-imino-sulphoxides, respectively. α-Cyanobenzyl sulphoxide racemizes through a h

Full text of DOI:10.1039/P19810000614

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