Enantioselective acyclic stereoselection under catalyst control - III. A very short asymmetric synthesis of the bryostatin C1-C9 segment using the chiral oxazaborolidinone-promoted aldol reaction

Article abstract of DOI:10.1016/S0957-4166(97)00461-8

A very short asymmetric synthesis of the bryostatin C₁-C₉ segment was achieved by three sequential chiral oxazaborolidinone-promoted aldol reactions under 'catalyst control'. This synthetic methodology is based on a direct asymmetric