Analgesic narcotic antagonists. 5. 7,7-Dimethyldihydrocodeinones and 7,7-dimethyldihydromorphinones

DOI: 10.1021/jm00138a015

Source and publish data:

Journal of Medicinal Chemistry p. 717 - 721 (1981)

Update date:2022-08-04

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Authors:

Leland Leland

Kotick Kotick

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Article abstract of DOI:10.1021/jm00138a015

Treatment of dihydrocodeinone or the 8β-methyl analogues with formaldehyde-Ca(OH)₂ in aqueous dioxane gave the corresponding 7,7-bis(hydroxymethyl) 6β-ols. Ditosylation of these, followed by LiEt₃BH reduction, gave either the 7,7-dim

Full text of DOI:10.1021/jm00138a015

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