NUCLEOPHILIC SUBSTITUTION OF ALCOHOL AT PHOSPHORUS OF SPIRO ACYLOXYPHOSPHORANE : TRANSPHOSPHORANYLATION

DOI: 10.1246/cl.1980.1599

Source and publish data:

Chemistry Letters p. 1599 - 1602 (1980)

Update date:2022-07-29

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Authors:

Kobayashi, Shiro

Narukawa, Yukitoshi

Hashimoto, Takatsugu

Saegusa, Takeo

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Article abstract of DOI:10.1246/cl.1980.1599

Spiro acyloxyphosphoranes (S-AOPs, 1 and 3) underwent the nucleophilic substitution of alcohols at the phosphorus atom to give another S-AOPs (2) (Transphosphoranylation).Reaction mechanism and characteristics of the transphosphoranylation are described.

Full text of DOI:10.1246/cl.1980.1599

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