Tetrahedron Letters p. 545 - 548 (1981)
Update date:2022-08-05
Topics:
Bailey, William F.
Croteau, Allan A.
The stereoelectronically controlled reaction of 2-methoxy-1,3-dioxane (1) with Grignard reagents does not follow the course suggested by the behavior of anancomeric models for the conformational isomers of 1.Treatment of 1 with RMgX leads to the predominant formation of acid labile 3-(1'-methoxyalkoxy)-1-propanols, derived from endocyclic cleavage of the ring C-O bond, and only minor amounts of the expected 2-R-1,3-dioxanes.
View MoreContact:+86-310-7092106
Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Dayang Chem (Hangzhou) Co.,Ltd.
website:http://www.dycnchem.com
Contact:+86-571-88938639
Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China
Contact:+8618766299236
Address:ROOM808, BUILDING2,NO.230 SHEN ZHEN ROAD, LAOSHAN DISTRICT
Contact:+86-310-7092106
Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Contact:21-7631221 15884421033
Address:326 Science and technology,Shanghai,China
Doi:10.1021/acs.jafc.0c04500
(2020)Doi:10.1039/P19810000712
(1981)Doi:10.1021/ja3100963
(2013)Doi:10.1016/S0040-4020(01)86182-2
(1988)Doi:10.1016/j.carres.2004.07.012
(2004)Doi:10.1039/b506131h
(2005)
