A Highly Stereoselective Synthesis of α-Glucosides from 1-O-Acetyl Glucose by Use of Tin(IV) Chloride - Silver Perchlorate Catalyst System

DOI: 10.1246/cl.1991.533

Source and publish data:

Chemistry Letters p. 533 - 536 (1991)

Update date:2022-09-26

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Authors:

Mukaiyama, Teruaki

Takashima, Tohru

Katsurada, Manabu

Aizawa, Hiroyuki

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Article abstract of DOI:10.1246/cl.1991.533

In the presence of a catalytic amount of tin(IV) species generated from tin(IV) chloride and silver perchlorate, 1-O-acetyl-D-glucose stereoselectively reacts with silyl alkoxides to give the corresponding α-glucosides in high yields.

Full text of DOI:10.1246/cl.1991.533

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