Reaction of tert-Butoxy Radicals with Phenols. Comparison with the Reactions of Carbonyl Triplets

DOI: 10.1021/ja00404a030

Source and publish data:

Journal of the American Chemical Society p. 4162 - 4166 (1981)

Update date:2022-08-02

Topics:

Authors:

Das, P. K.

Encinas, M. V.

Steenken, S.

Scaiano, J. C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00404a030

Tert-butoxy radicals generated in the photodecomposition of di-tert-butyl peroxide react efficiently with phenols to yield the corresponding phenoxy radicals.Typical rate constants in benzene at 22 deg C are 3.3x10⁸ and 1.6x10⁹ M View More

Full text of DOI:10.1021/ja00404a030

Products guided by the article

Product name:Phenoxy, 4-ethyl-

Cas No:78165-02-3

R&D Labs maybe for 78165-02-3

Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:

Relevant to this article

Synthesis, physicochemical and biochemical studies of 1′,2′- oxetane constrained adenosine and guanosine modified oligonucleotides, and their comparison with those of the corresponding cytidine and thymidine analogues

Doi:10.1021/ja048417i
(2004)
Effect of Substituents in the 5' and 7' Positions on the Spectra of Merocyanines of 1,3,3-Trimethyl-6'-nitroindoline-2-spiro-2'-<2H>-chromenes

Doi:10.1007/BF00503335
(1981)
Reaction of Olivanic Acids with Hypobromous Acid: The Preparation and Use of a Versatile Intermediate, the C-3 Thiol

Doi:10.1039/c39810000803
(1981)
Novel chemical modifications at the 4-position of chromones. Synthesis and reactivity of 4H-chromene-4-spiro-5′-isoxazolines and related compounds

Doi:10.1016/j.tetlet.2004.07.158
(2004)
Syntheses of 1,6-dimethylpyrimido[4,5-c]pyridazine-5,7(1H, 6H)-diones (4-deazatoxoflavins) and their use in the autorecycling oxidation of alcohols and amines

Doi:10.1248/cpb.29.379
(1981)
A General Synthetic Method for α-Methylene Compounds by the Palladium-Catalyzed Decarboxylation-Deacetoxylation of Allyl α-Acetoxymethylcarboxylates Substituted by an Electron-Withdrawing Group at α-Position

Doi:10.1246/cl.1987.23
(1987)

Article Doi