Reaction of tert-Butoxy Radicals with Phenols. Comparison with the Reactions of Carbonyl Triplets

DOI: 10.1021/ja00404a030

Source and publish data:

Journal of the American Chemical Society p. 4162 - 4166 (1981)

Update date:2022-08-02

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Authors:

Das, P. K.

Encinas, M. V.

Steenken, S.

Scaiano, J. C.

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Article abstract of DOI:10.1021/ja00404a030

Tert-butoxy radicals generated in the photodecomposition of di-tert-butyl peroxide react efficiently with phenols to yield the corresponding phenoxy radicals.Typical rate constants in benzene at 22 deg C are 3.3x10⁸ and 1.6x10⁹ M View More

Full text of DOI:10.1021/ja00404a030

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