Chemistry Letters p. 23 - 24 (1987)
Update date:2022-08-02
Topics: Palladium catalyst Decarboxylation Electron-withdrawing group Synthetic method
Tsuji, Jiro
Nisar, Mohammad
Minami, Ichiro
Allyl α-acetoxymethylcarboxylates substituted by ester, amide, nitro, cyano, and sulfonyl groups at α-position undergo smooth palladium-catalyzed decarboxylation-deacetoxylation under mild neutral conditions to afford corresponding α-methylene compounds in high yields.
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